Laser microprobe facility used in the elemental analysis of small feature of a sample

Laser microprobe facility is effective in the elemental analysis of small areas of heterogeneous samples. The instrument uses the focused beam of a pulsed laser to evaporate a small volume of material from a relatively massive sample

Paving the Way for Success in High School and Beyond: The Importance of Preparing Middle School Students for the Transition to Ninth Grade

P/PV's GroundWork series summarizes available evidence on a variety of social policy topics, providing a firm foundation for future work.This second brief in the series presents an overview of issues surrounding the ninth grade transition: why it is so important; why many middle school students find it so difficult; traits related to a successful transition; and what schools can do to ease difficulties in the transition. Research indicates that students unprepared to handle the transition are more likely to disengage from school, which in turn may lead to dropping out -- and a host of related problems, thus perpetuating a cycle of poverty for disadvantaged, low-income youth

The Case for School-Based Integration of Services: Changing the Ways Students, Families and Communities Engage with their Schools

P/PV's GroundWork series summarizes available evidence on a variety of social policy topics, providing a solid foundation for future work.This first issue reviews the current literature about the potential benefits of simultaneously providing three services in school -- healthcare, out-of-school-time learning and family supports -- to boost students' educational outcomes. For disadvantaged, low-income youth, research indicates that access to these supports can play a key role in helping them surmount common obstacles to educational attainment. In addition to highlighting how each affects key outcomes such as learning, school connectedness (i.e., positive feelings about school) and access to needed services, this brief summarizes the potential benefits of offering these resources through a highly integrated, school-based model

Calculation of a separated turbulent boundary layer

The properties of a Navier-Stokes solution of a shock-separated turbulent flow over a flat wall are investigated. Refinements of an algebraic relaxation turbulence model previously shown to be of value for the simulation of separated flows are presented. A simplified analysis applicable near an adiabatic wall is developed and used to help verify the accuracy of the numerical solution. Features of the time-dependent response of a turbulent boundary layer to shock impingement are presented

Simulator evaluation of display concepts for pilot monitoring and control of space shuttle approach and landing. Phase 2: Manual flight control

A study of the display requirements for final approach management of the space shuttle orbiter vehicle is presented. An experimental display concept, providing a more direct, pictorial representation of the vehicle's movement relative to the selected approach path and aiming points, was developed and assessed as an aid to manual flight path control. Both head-up, windshield projections and head-down, panel mounted presentations of the experimental display were evaluated in a series of simulated orbiter approach sequence. Data obtained indicate that the experimental display would enable orbiter pilots to exercise greater flexibility in implementing alternative final approach control strategies. Touchdown position and airspeed dispersion criteria were satisfied on 91 percent of the approach sequences, representing various profile and wind effect conditions. Flight path control and airspeed management satisfied operationally-relevant criteria for the two-segment, power-off orbiter approach and were consistently more accurate and less variable when the full set of experimental display elements was available to the pilot. Approach control tended to be more precise when the head-up display was used; however, the data also indicate that the head-down display would provide adequate support for the manual control task

Improved display support for flight management during low visibility approach and landing. A simulator evaluation of an ILS-independent runway perspective display Final report

Low visibility approach and landing simulation for jet transport

Cationic Alkylaluminum-Complexed Zirconocene Hydrides as Participants in Olefin Polymerization Catalysis

The alkylaluminum-complexed zirconocene trihydride cation [(SBI)Zr(μ-H)_3(AliBu_2)_2]^+, which is obtained by reaction of (SBI)ZrCl_2 with [Ph_3C][B(C_6F_5)_4] and excess HAl^iBu_2 in toluene solution, catalyzes the formation of isotactic polypropene when exposed to propene at -30 °C. This cation remains the sole observable species in catalyst systems free of AlMe compounds. In the presence of AlMe_3, however, exposure to propene causes the trihydride cation to be completely converted, under concurrent consumption of all hydride species by propene hydroalumination, to the doubly Me-bridged cation [(SBI)Zr(μ-Me)_2AlMe_2]^+. The latter then becomes the resting state for further propene polymerization, which produces, by chain transfer to Al, mainly AlMe_2-capped isotactic polypropene

Alkylaluminum-complexed zirconocene hydrides: identification of hydride-bridged species by NMR spectroscopy

Reactions of unbridged zirconocene dichlorides, (R_nC_5H_5−n)_2ZrCl_2 (n = 0, 1, or 2), with diisobutylaluminum hydride (HAl^iBu_2) result in the formation of tetranuclear trihydride clusters of the type (R_nC_5H_5−n)_2Zr(μ-H)_3(Al^iBu_2)_3(μ-Cl)_2, which contain three [Al^iBu_2] units. Ring-bridged ansa-zirconocene dichlorides, Me_2E(R_nC_5H_4−n)_2ZrCl_2 with E = C or Si, on the other hand, are found to form binuclear dihydride complexes of the type Me_2E(R_nC_5H_4−n)_2Zr(Cl)(μ-H)_2Al^iBu_2 with only one [Al^iBu_2] unit. The dichotomy between unbridged and bridged zirconocene derivatives with regard to tetranuclear versus binuclear product formation is proposed to be connected to different degrees of rotational freedom of their C_5-ring ligands. Alkylaluminum-complexed zirconocene dihydrides, previously observed in zirconocene-based precatalyst systems activated by methylalumoxane (MAO) upon addition of HAl^iBu_2 or Al^iBu_3, are proposed to be species of the type Me_2Si(ind)_2Zr(Me)(μ-H)_2Al^iBu_2, stabilized by interaction of their terminal Me group with a Lewis acidic site of MAO